Selective determination of oxygenates in complex samples with the O-FID analyzer

Autor:	A. Sironi, J. Ch. Frohne, G. R. Verga, Werner Schneider
Rok vydání:	1988
Předmět:	Spectrum analyzer Chromatography General Chemical Engineering Analytical chemistry law.invention chemistry.chemical_compound chemistry Linear range law Octane rating Flame ionization detector Microreactor Gasoline Oxygenate Octane
Zdroj:	Journal of High Resolution Chromatography. 11:248-252
ISSN:	1521-4168 0935-6304
Popis:	A gas-chromatographic analyzer allowing the selective detection of individual oxygenates in complex organic mixtures, such as gasolines, is described. The analyzer is based on the oxygen-specific response flame ionization detection (O-FID) method. The system operates with capillary columns and includes a cracking reactor to convert any oxygenate to carbon monoxide and a special FID equipped with a microreactor for the catalytic hydro-genation of CO and detection as methane. Hydrocarbons give no signal. The selectivity of the method is better than 1:107 and the linear range approaches 105. The analysis of modern fuels containing oxygenated additives, to improve octane ratings, may greatly benefit from the proposed analytical method.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a5b0c6d89e7d2cc3dbd0cff20d9b0fab https://doi.org/10.1002/jhrc.1240110306 Zobrazit plný text záznamu Plný text