Diastereoselective Synthesis of (±)-Ambrox by Titanium(III)-Catalyzed Radical Tandem Cyclization

Autor:	Laura Pozo-Morales, Roman Rodríguez-Maecker, J. Enrique Oltra, Ignacio Rodríguez-García, Esther Roldan-Molina, L. A. R. Foley, Natalia M. Padial, Iris Sancho-Sanz, Juan Muñoz-Bascón, Adriana Irías-Álvarez, Antonio Rosales
Rok vydání:	2015
Předmět:	chemistry.chemical_compound Tandem Chemistry Stereochemistry Radical Organic Chemistry chemistry.chemical_element Farnesol Radical cyclization Derivative (chemistry) Titanium Catalysis
Zdroj:	Synlett. 27:369-374
ISSN:	1437-2096 0936-5214
Popis:	A synthesis of (±)-ambrox, a compound with delicious ambergris-type scent, is presented. The key step is a highly diastereoselective titanocene(III)-catalyzed radical tandem cyclization of a farnesol derivative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a56c39204d61e5eb238ef44a53c5c78f https://doi.org/10.1055/s-0035-1560594 Zobrazit plný text záznamu