Autor:	Anita Coetzee, Ayesha Jacobs, Susan A. Bourne
Rok vydání:	2000
Předmět:	Crystallography chemistry.chemical_compound Tetrahydrate Dehydration reaction Chemistry Kinetics medicine Dehydration Methanol Crystal structure medicine.disease Powder diffraction Monoclinic crystal system
Zdroj:	Journal of Inclusion Phenomena and Macrocyclic Chemistry. 36:217-228
ISSN:	0923-0750
DOI:	10.1023/a:1008016530138
Popis:	Thiothixeneβ2HCl forms three different hydrates on exposure to water vapour. These have been characterised by X-ray powder diffraction. The dehydration reaction of the monohydrate follows the first-order rate law with Ea = 125(22) kJ mol-1. The dehydration of the tetrahydrate follows a complex mechanism. The crystal structure of the methanol solvate of thiothixeneβ2HCl has been elucidated. It is monoclinic, P21/c, a = 18.870, b = 7.018, c = 21.913 A, β = 105.622°.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a56b39f110a1d802061a24a1a843cf3b https://doi.org/10.1023/a:1008016530138 Zobrazit plný text záznamu