The enthalpy of formation of π-allylpalladium(I ) chloride dimer and the palladium–allyl bond energy
| Autor: | S. J. Ashcroft, C. T. Mortimer |
|---|---|
| Rok vydání: | 1971 |
| Předmět: |
Chemistry
Dimer Inorganic chemistry chemistry.chemical_element Chloride Bond-dissociation energy Standard enthalpy of formation Inorganic Chemistry chemistry.chemical_compound Differential scanning calorimetry medicine Physical chemistry Physical and Theoretical Chemistry Bond energy Standard enthalpy change of formation medicine.drug Palladium |
| Zdroj: | J. Chem. Soc. A. :781-783 |
| ISSN: | 0022-4944 |
| Popis: | The enthalpies of formation of crystalline (–107·6 ± 1·7 kJ mol–1) and gaseous (+18 ± 2·5 kJ mol–1)[π-C3H5PdCl]2 have been determined by differential scanning calorimetry. A minimum value of 237 kJ mol–1 is calculated for the palladium–allyl bond dissociation energy. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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