ChemInform Abstract: Stereochemical Effects of Trimethylsilyl Chloride (TMSCl) on the Conjugate Addition of Organocopper Reagents

Autor:	Pierre Mangeney, Alexandre Alexakis, R. Sedrani
Rok vydání:	1990
Předmět:	Steric effects chemistry.chemical_compound Trimethylsilyl chloride chemistry Reagent Chelation General Medicine Medicinal chemistry Conjugate
Zdroj:	ChemInform. 21
ISSN:	0931-7597
DOI:	10.1002/chin.199039142
Popis:	The stereochemical course of the conjugate addition of organocopper reagents, in the presence of TMSCl, is not affected by remote chelation effects, whereas in its absence, the latter may predominate. By this way, it is possible to distinguish, the relative effects of the chelation and of the steric hindrance.
Databáze:	OpenAIRE
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