Autor: |
R. Lapouyade, Claude Rullière, Renaud Mathevet, J.‐F. Létard, Gediminas Jonusauskas |
Rok vydání: |
1996 |
Předmět: |
|
Zdroj: |
AIP Conference Proceedings. |
ISSN: |
0094-243X |
DOI: |
10.1063/1.50213 |
Popis: |
The Intramolecular Charge Transfer (ICT) rate in the excited state of 4‐(N‐monoaza‐15‐crown‐5) 4′‐cyano stilbene, a polar fluoroionophore of the stilbene‐crown series, has been measured by sub‐picosecond absorption spectroscopy from its complex with Ag+ in methanol and the results are compared with those reported from the complex with Ca2+ in acetonitrile and butyronitrile. In any case the ICT state occurs through three intermediates distinguished by their absorption spectra and lifetime. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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