Sub-picosecond dynamics of stepwise release of calcium from intrinsic fluorescence probes

Autor: R. Lapouyade, Claude Rullière, Renaud Mathevet, J.‐F. Létard, Gediminas Jonusauskas
Rok vydání: 1996
Předmět:
Zdroj: AIP Conference Proceedings.
ISSN: 0094-243X
DOI: 10.1063/1.50213
Popis: The Intramolecular Charge Transfer (ICT) rate in the excited state of 4‐(N‐monoaza‐15‐crown‐5) 4′‐cyano stilbene, a polar fluoroionophore of the stilbene‐crown series, has been measured by sub‐picosecond absorption spectroscopy from its complex with Ag+ in methanol and the results are compared with those reported from the complex with Ca2+ in acetonitrile and butyronitrile. In any case the ICT state occurs through three intermediates distinguished by their absorption spectra and lifetime.
Databáze: OpenAIRE