Why Less Coordination Provides Higher Reactivity Chromium Phosphinoamidine Ethylene Trimerization Catalysts

Autor:	Johnathan C. Stanley, Daniel H. Ess, Doo-Hyun Kwon, Steven M. Bischof, Orson L. Sydora, Steven M. Maley
Rok vydání:	2020
Předmět:	Ethylene 010405 organic chemistry chemistry.chemical_element General Chemistry 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound Chromium chemistry Polymer chemistry Density functional theory Reactivity (chemistry) Phosphine
Zdroj:	ACS Catalysis. 10:9674-9683
ISSN:	2155-5435
Popis:	Cr phosphine catalysts are uniquely suited for industrial selective ethylene trimerization to 1-hexene. We recently introduced a Cr N-phosphinoamidine catalyst ((P,N)Cr) transition-state model for ...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a5399cd200f57ea24878f440178b1cdd https://doi.org/10.1021/acscatal.0c02595 Zobrazit plný text záznamu