Concentration-dependent emissive lignin-derived graphene quantum dots for bioimaging and anti-counterfeiting
Autor: | Liang Jiao, Xiao Tianhua, Min Yonggang, Ziyu Guo, Hairui Ji, Ruibin Wang, Yanlin Qin, Hongqi Dai, Yuqian Liu, Feiguo Hua |
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Rok vydání: | 2021 |
Předmět: |
Photoluminescence
Materials science Nanotechnology 02 engineering and technology engineering.material 010402 general chemistry 01 natural sciences law.invention chemistry.chemical_compound law Materials Chemistry Lignin Electrical and Electronic Engineering Graphene Depolymerization Mechanical Engineering Hydrotrope General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences Electronic Optical and Magnetic Materials Concentration dependent chemistry Quantum dot engineering Biopolymer 0210 nano-technology |
Zdroj: | Diamond and Related Materials. 117:108482 |
ISSN: | 0925-9635 |
Popis: | Graphene quantum dots (GQDs) derived from lignin, which is the most naturally abundant aromatic biopolymer on earth, have found promising application in many fields. Here, we demonstrate that GQDs with concentration-dependent photoluminescence emission can be produced from lignin by employing a non-oxidative method. In brief, o-aminobenzenesulfonic acid was used as an acidic hydrotrope for lignin depolymerization, followed by a conventional hydrothermal treatment. Detailed investigations indicated that the observed concentration-dependent feature for GQDs was attributed to the stack of graphene basal plane and the interaction of functional groups. Moreover, it was found that the concentration-dependent emissive GQDs were endowed with ultralong-term photostability (12 months) and negligible cytotoxicity, promising them potential applications in anti-counterfeiting and bioimaging. Overall, this study develops a feasible and sustainable strategy for opening up enormous opportunities to use renewable lignin-derived GQDs for more technological applications. |
Databáze: | OpenAIRE |
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