Conversion of Ethanol and Acetaldehyde to 1, 3-Butadiene Catalyzed by Zr–Si Materials
| Autor: | Minhua Zhang, Meixiang Gao, Haoxi Jiang |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Ethanol
Acetaldehyde 1 3-Butadiene 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Desorption Pyridine Lewis acids and bases 0210 nano-technology Selectivity Nuclear chemistry |
| Zdroj: | Catalysis Surveys from Asia. 22:222-229 |
| ISSN: | 1574-9266 1571-1013 |
| Popis: | Series of ZrO2 supported on the different kinds of SiO2 carriers were applied in the reaction of 1, 3-butadiene formation from ethanol and acetaldehyde. ZrO2/Nano-SiO2 performed the best performance with the 1, 3-butadiene selectivity 91.43% and the total conversation 52.39%. Prepared catalysts were characterized by N2 adsorption–desorption, TEM, XRD, temperature-programmed desorption of NH3 and CO2, FTIR spectroscopy of adsorbed pyridine and CO2, Raman XPS. The results show that the weak Lewis acid and basic sites are appropriate for BD formation. Furthermore, more and balance acid-basic sites are rather important for the reaction of ethanol and acetaldehyde conversion to BD. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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