Phenylhydrosilocane as a source of silatranylium cations

Autor:	T. A. Kochina, V. S. Fundamensky, V. V. Avrorin, Igor S. Ignatyev
Rok vydání:	2016
Předmět:	Quantum chemical chemistry.chemical_compound Carbon group Atrane 010405 organic chemistry Chemistry Phase (matter) Inorganic chemistry General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Ion
Zdroj:	Russian Chemical Bulletin. 65:1047-1052
ISSN:	1573-9171 1066-5285
Popis:	Quantum chemical calculations were used for comparative analysis of the cations of the atrane structure [M(OCH2CH2)3N]+ (M = Si or Ge) with classic three-coordinate cations R3M+ of Group 14 elements. The possibility of nuclear chemical generation of atranylium cations in the condensed phase was experimentally demonstrated with silatranylium ions as examples.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a52d39433a6b680794e2acfd59b3e312 https://doi.org/10.1007/s11172-016-1411-2 Zobrazit plný text záznamu Full text from SpringerLink