Planar Complexes Containing Metal-Metal Bonds

Autor:	K. Krogmann
Rok vydání:	1969
Předmět:	Inorganic chemistry chemistry.chemical_element General Medicine General Chemistry Catalysis Metal Bond length Crystallography Planar chemistry visual_art visual_art.visual_art_medium Metal metal Partial oxidation Platinum
Zdroj:	Angewandte Chemie International Edition in English. 8:35-42
ISSN:	1521-3773 0570-0833
DOI:	10.1002/anie.196900351
Popis:	Planar complexes, and particularly those of platinum, can form structures containing linear chains of heavy metal atoms with metal-metal distances as short as 3.1 A. The bonding in these chains can be strengthened by partial oxidation, and the bond lengths can be reduced to 2.8 A in this way. Model structures for the novel nonstoichiometric products, such as K2[Pt(CN)4]Cl0·32 · 2.6 H2O, are considered. The bonding is also discussed on the basis of a one-dimensional band model.
Databáze:	OpenAIRE
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