Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives
| Autor: | Bryan D. Koivisto, Alan J. Lough, J. K. Singh, J. T. H. Pau, Burhan A Hussein, J. S. Dhindsa, Devin D. Machin, Jeanette A. Adjei, Malek El-Aooiti, S. R. Sritharan |
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| Rok vydání: | 2017 |
| Předmět: |
Nucleophilic addition
010405 organic chemistry General Chemical Engineering Imine General Chemistry 010402 general chemistry Ring (chemistry) Electrochemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound chemistry Aldol reaction Wittig reaction Organic chemistry Knoevenagel condensation BODIPY |
| Zdroj: | RSC Advances. 7:8922-8926 |
| ISSN: | 2046-2069 |
| Popis: | The synthesis and characterization of a family of 2-substituted BODIPY dyes are reported herein. The dyes have been prepared using nucleophilic addition reactions (Wittig reactions, imine, Knoevenagel & aldol condensations) which are typically more challenging for BODIPY ring systems. Structure–property relationships have also been delineated by evaluating the physicochemical properties including; absorption & emission spectroscopy, electrochemical studies (CV, DPV) and theoretical calculations (TD-DFT). |
| Databáze: | OpenAIRE |
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