Interaction of divalent metal ions with D-aldonic acids in the solid phase-II. Structural information
| Autor: | Juan Manuel Salas Peregrín, Sandra Signorella, Virtudes Moreno, Luis F. Sala, Alejandro A. Frutos, Graciela M. Escandar |
|---|---|
| Rok vydání: | 1998 |
| Předmět: |
Thermogravimetric analysis
Chemistry Metal ions in aqueous solution Analytical chemistry Magnetic susceptibility law.invention Inorganic Chemistry Metal law visual_art Divalent metal ions Phase (matter) Materials Chemistry visual_art.visual_art_medium Diffuse reflection Physical and Theoretical Chemistry Electron paramagnetic resonance Nuclear chemistry |
| Zdroj: | Polyhedron. 17:3371-3378 |
| ISSN: | 0277-5387 |
| DOI: | 10.1016/s0277-5387(98)00119-3 |
| Popis: | Complexes formed between d -glucoheptonate, d -galactonate, d -gulonate and d -ribonate, and several metal ions were obtained in the solid state. Specifically: d -glucoheptonates, Be(C 7 H 13 O 8 ) 2 · 1\2H 2 O, Mn(C 7 H 13 O 8 ) 2 · 2H 2 O, Co(C 7 H 13 O 8 ) 2 · 2H 2 O, Ni(C 7 H 13 O 8 ) 2 · 2H 2 O, Cu(C 7 H 13 O 8 ) 2 · 2H 2 O, Pb(C 7 H 13 O 8 ) 2 ; d -galactonates, Mn(C 6 H 11 O 7 ) 2 · 2H 2 O, Co(C 6 H 11 O 7 ) 2 · 3H 2 O, Ni(C 6 H 11 O 7 ) 2 · 3H 2 O, Cu(C 6 H 11 O 7 ) 2 , Pb(C 6 H 11 O 7 ) 2 ; d -gulonates, Co(C 6 H 11 O 7 ) 2 · H 2 O, Ni(C 6 H 11 O 7 ) 2 · 2H 2 O, Cu(C 6 H 11 O 7 ) 2 · 2H 2 O; d -ribonates, Mn(C 5 H 9 O 6 ) 2 , Co(C 5 H 9 O 6 ) 2 · 2H 2 O, Ni(C 5 H 9 O 6 ) 2 · 2H 2 O, Cu(C 5 H 9 O 6 ) 2 .2H 2 O and Pb(C 5 H 9 O 6 ) 2 have been isolated. These metal sugar salts were characterized by elemental analysis, thermogravimetric analysis, magnetic susceptibility measurements, FT–IR, diffuse reflectance and EPR spectroscopies. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect