Synthesis and structural characterization of zinc(II) coordination compounds with pyterpy; new precursors for preparation of zinc(II) oxide nano-particles with different morphologies

Autor:	Azadeh Mehrani, Parisa Ebrahimpour, Ali Morsali
Rok vydání:	2013
Předmět:	chemistry.chemical_classification Ligand Inorganic chemistry Nanoparticle chemistry.chemical_element Infrared spectroscopy Crystal structure Zinc Coordination complex law.invention chemistry law Materials Chemistry Calcination Physical and Theoretical Chemistry Powder diffraction Nuclear chemistry
Zdroj:	Journal of Coordination Chemistry. 66:856-867
ISSN:	1029-0389 0095-8972
DOI:	10.1080/00958972.2013.766334
Popis:	4′-(4-pyridyl)-2,2′ : 6′,2″-terpyridine (pyterpy) was used as a ligand for preparing three zinc(II) coordination polymers, [Zn(pyterpy)(OAc)]ClO4 (1), [Zn(pyterpy)I2] (2), and [Zn(pyterpy)2](ClO4)2·(H2O)2.9 (3). The two first coordination polymers were synthesized by slow evaporation while the last was prepared through hydrothermal method; all were characterized by IR spectroscopy and elemental analysis. The structures of 1–3 were determined by single-crystal X-ray diffraction. Pure phase ZnO nanoparticles with different sizes and morphologies were obtained by direct calcination of 1–3 and characterized by X-ray powder diffraction pattern and scanning electron microscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a4fa504986ffe261bbd2b3fabf729392 https://doi.org/10.1080/00958972.2013.766334 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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