Autor: |
Martin Jungen, René Bär, Kurt Börlin, Thomas Heinis |
Rok vydání: |
1985 |
Předmět: |
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Zdroj: |
Chemical Physics. 94:235-245 |
ISSN: |
0301-0104 |
Popis: |
Photoionization efficiencies for the various fragments of 1.1-difluuoroethane (Freon 152 A) as well as the threshold photoelectron spectrum at photon energies between 10 and 20 eV have been measured. The appearance energy of the parent ion AP = 11.865 eV and Δ 1 H 2?? o = 644.0±6 kJ/mol. A number of excess-energy corrections for fragmentation reactions have been obtained and the decomposition of the CH 3 CHF 2 + ion is documented with energy derivatives of the photoionization efficiencies and a breakdown diagram. At photon energies above 16 eV isolated-state behaviour was detected. |
Databáze: |
OpenAIRE |
Externí odkaz: |
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