Citral oxide and some of its reactions

Autor:	V. N. Samsonova, L. A. Yanovskaya, L. P. Glushko, M. S. Malinovskii
Rok vydání:	1980
Předmět:	chemistry.chemical_classification Double bond Hydrogen Acetoacetic ester synthesis Oxide chemistry.chemical_element General Chemistry Citral Catalysis chemistry.chemical_compound chemistry Organic chemistry Ethyl chloroacetate Hydrogen peroxide
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 29:754-757
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00949679
Popis:	1. A new method was proposed for the synthesis of citral oxide by the oxidation of citral with hydrogen peroxide under interphase catalysis conditions. 2. Citral oxide condenses with acetoacetic ester under interphase catalysis conditions without opening the oxirane ring. 3. The reaction of citral oxide with orthoformic ester, ethyl chloroacetate, and carbethoxymethylenephosphorane proceeds only at the carbonyl group. 4. The epoxidation and dichloromethylenation of the ethyl ester of 4,5-epoxy-5,9-dimethyl-2, 8-decadienoic acid is realized only at the more remote double bond.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a4e146f64823d74e4a1b332fa3d0f927 https://doi.org/10.1007/bf00949679 Zobrazit plný text záznamu Full text from SpringerLink