Labile η6-areneruthenium sulfide clusters. Crystal structure of [(C6H6)4Ru5S4](PF6)2 and [(C6H6)4Ru4S5](PF6)2
| Autor: | Artem L. Gushchin, Pavel A. Abramov, Vladimir S. Korenev, Maxim N. Sokolov, N. B. Kompankov, D.G. Sheven |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Sulfide 010405 organic chemistry Organic Chemistry Solid-state Crystal structure 010402 general chemistry 01 natural sciences Biochemistry Redox 0104 chemical sciences Inorganic Chemistry Crystallography chemistry Materials Chemistry Physical and Theoretical Chemistry Cyclic voltammetry |
| Zdroj: | Journal of Organometallic Chemistry. 867:347-352 |
| ISSN: | 0022-328X |
| Popis: | A new labile areneruthenium sulfide complex, [(C6H6)3Ru3S2](PF6)2 (1), was prepared and characterized both in solid state and in solution. Light-driven de-coodination of the arene ligands has been demonstrated. Two new polynuclear areneruthenium complexes, [(C6H6)4Ru5S4](PF6)2·2CH3CN (2) and [(C6H6)4Ru4S5](PF6)2·1.25CH3CN·0.5H2O (3), were obtained from 1 and structurally characterized. Redox behaviour of [(C6H6)3Ru3S2](PF6)2 and [Ru5S4(C6H6)4](PF6)2·2CH3CN was studied by cyclic voltammetry and reveals one reversible reduction wave. |
| Databáze: | OpenAIRE |
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