A new multicomponent reaction for direct synthesis of primary γ-nitroamides

Autor:	Dennis Russowsky, Caroline Da Ros Montes D’Oca, Esthéfani P. Guedes, Marcelo Gonçalves Montes D'Oca, Jessica Caroline Dias da Silva, Leonardo S. Santos, Fabiane M. Nachtigall
Rok vydání:	2016
Předmět:	Ammonium carbonate Primary (chemistry) Nitromethane 010405 organic chemistry Chemistry General Chemical Engineering Electrospray ionization General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences chemistry.chemical_compound Yield (chemistry) Organic chemistry
Zdroj:	RSC Advances. 6:98427-98433
ISSN:	2046-2069
DOI:	10.1039/c6ra22141f
Popis:	A new multicomponent reaction for direct synthesis of γ-nitroamides promoted by ammonium carbonate was developed. A series of γ-nitroamides were synthesized in 35–93% yield from Meldrum's acid, aromatic or aliphatic aldehydes, nitromethane and ammonium carbonate. A mechanistic pathway was proposed based on electrospray ionization mass spectrometry (ESI/MS) experiments.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a4d2c9dd0e8268df81fe2037d39ff1c7 https://doi.org/10.1039/c6ra22141f Zobrazit plný text záznamu