Spectroscopic determination of dipole-dipole interaction in solutions of trioctylammonium halides

Autor:	Kh. P. Oya, Gleb S. Denisov, E. V. Ryl'tsev, D. N. Suglobov
Rok vydání:	1972
Předmět:	chemistry.chemical_classification Absorption spectroscopy Chemistry Inorganic chemistry Iodide Infrared spectroscopy Halide General Chemistry Chloride Spectral line Dipole chemistry.chemical_compound Bromide medicine medicine.drug
Zdroj:	Theoretical and Experimental Chemistry. 5:164-167
ISSN:	1573-935X 0040-5760
DOI:	10.1007/bf00528041
Popis:	Dimerization energies of trioctylammonium halides in carbon tetrachloride solution, associated as a result of dipole-dipole interaction, were calculated from the infrared absorption spectra. The values obtained were 5, 4, and 1.5 kcal/mole for the chloride, bromide, and iodide, respectively. The calculation showed that the dimers of these salts are contact dimers.
Databáze:	OpenAIRE
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