Transient species of importance in the stoichiometric hydroformylation reaction I. Evidence for HCo(CO)3 by matrix isolation

Autor:	Bruce S. Ault, Paul Wermer, Milton Orchin
Rok vydání:	1978
Předmět:	Argon Chemistry Organic Chemistry Matrix isolation chemistry.chemical_element Photochemistry Biochemistry Spectral line Inorganic Chemistry Matrix (chemical analysis) Materials Chemistry Irradiation Physical and Theoretical Chemistry Stoichiometry Hydroformylation
Zdroj:	Journal of Organometallic Chemistry. 162:189-194
ISSN:	0022-328X
Popis:	Spectra of HCo(CO) 4 in a low temperature argon matrix show a weak band at 2018 cm −1 . On irradiation, this band grows rapidly and additional bands (previously too weak to be readily observable) appear at 2025 and 485 cm −1 . These three bands are assigned to HCo(CO) 3 , a coordinatively unsaturated species persistently proposed as an intermediate in the hydroformylation reaction but not previously characterized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a4a4cb415fc17ced72c283061982c25e https://doi.org/10.1016/s0022-328x(00)82037-9 Zobrazit plný text záznamu