Frontispiece: Utilizing Palladium-Stabilized Zwitterions for the Construction of N-Heterocycles

Autor:	Christopher P. Lakeland, Joseph P. A. Harrity, Benjamin D. W. Allen
Rok vydání:	2017
Předmět:	Nucleophile Chemistry Organic Chemistry Electrophile Enantioselective synthesis Organic chemistry chemistry.chemical_element General Chemistry Catalysis Cycloaddition Palladium
Zdroj:	Chemistry - A European Journal. 23
ISSN:	0947-6539
DOI:	10.1002/chem.201785662
Popis:	Pd catalysis provides a convenient method for the generation of zwitterionic intermediates that offer significant opportunities for the synthesis of functionalized heterocycles. The combination of electrophilic π‐allyl Pd fragments and C‐, N‐ and O‐centered nucleophiles allows these intermediates to react with readily available substrates to furnish a range of high value products with control of chemo‐, regio‐ and stereo‐selectivity.
Databáze:	OpenAIRE
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