Synthesis and Characterization of Oxotitanium(IV) and Oxovanadium(IV) Complexes of Arylbis(5-hydroxy-3-methyl-1-phenyl-4-pyrazolyl)methane Ligands
| Autor: | Shaker L. Stefan, Moheb F. Ishak |
|---|---|
| Rok vydání: | 1994 |
| Předmět: |
Chemistry
Ligand Thermal decomposition Infrared spectroscopy chemistry.chemical_element Medicinal chemistry Oxygen Methane Inorganic Chemistry Metal chemistry.chemical_compound Elemental analysis visual_art Differential thermal analysis visual_art.visual_art_medium Organic chemistry Physical and Theoretical Chemistry |
| Zdroj: | Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 24:845-853 |
| ISSN: | 1532-2440 0094-5714 |
| DOI: | 10.1080/00945719408001305 |
| Popis: | The interactions of oxotitanium(IV) and oxovanadium(IV) with arylbis (5-hydroxy-3-methyl-1-phenyl-4-pyrazolyl)methane (ArBPyM) ligands containing enolic oxygen donors, have been studied with ir spectroscopy, thermogravi-metric measurements and elemental analysis. The results indicate the probable formation of dimeric complexes (metal: ligand ratio = 1:1) through bridging sulfato ligand. Application of differential thermal analysis allowed determination of the mechanism of thermal decomposition of the complexes. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|