Synthesis and crystal structure of Isotrithionedithiolato-bis(phenanthroline)zinc(II)

Autor:	O. S. Pyshkin, V. A. Starodub, S. V. Vitushkina
Rok vydání:	2006
Předmět:	Stereochemistry Ligand Chemistry General Chemical Engineering Phenanthroline chemistry.chemical_element General Chemistry Crystal structure Zinc Sulfur Crystallography chemistry.chemical_compound Ultraviolet visible spectroscopy Octahedron Monoclinic crystal system
Zdroj:	Russian Journal of Coordination Chemistry. 32:237-241
ISSN:	1608-3318 1070-3284
DOI:	10.1134/s1070328406040026
Popis:	The synthesis of a mixed-ligand complex 1,3-dithiole-2-thione-4,5-dithiolato-bis(1,10-phenanthroline)zinc(II), [Zn(Dmit)(Phen)2], is described. The crystals are monoclinic, space group P21/n, a = 11.868(2) A, b = 13.122(3) A, c = 17.010(3) A, β = 102.01(3)°, Z = 4. The coordination polyhedron of the Zn(II) atom is an octahedron formed by two sulfur atoms of the Dmit ligand and four nitrogen atoms of the two Phen ligands. The complex is studied by IR and UV spectroscopy.
Databáze:	OpenAIRE
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