Synthesis and Structures of Two Ba(II) Metal–Organic Frameworks Based on Pyridine-2,6-Dicarboxylic Acid N-Oxide
| Autor: | Fang-Ming Wang, Lili Wen, Miao-Miao Wang, Huizhen Zhu, Qingjin Meng, Xiao-Ke Leng |
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| Rok vydání: | 2010 |
| Předmět: |
chemistry.chemical_classification
Alkaline earth metal Materials science Polymers and Plastics Inorganic chemistry Oxide Crystal structure Hydrothermal circulation chemistry.chemical_compound Dicarboxylic acid chemistry Yield (chemistry) Pyridine Polymer chemistry Materials Chemistry Metal-organic framework |
| Zdroj: | Journal of Inorganic and Organometallic Polymers and Materials. 20:313-319 |
| ISSN: | 1574-1451 1574-1443 |
| Popis: | Hydrothermal and solution reactions of pyridine-2,6-dicarboxylic acid N-oxide (2,6-PDCO) and BaCl2·2H2O yield two metal–organic frameworks; namely [Ba(2,6-PDCO)]n (1) and [Ba(2,6-PDCO)·H2O]n (2), respectively. Single-crystal X-ray analyses reveal that compound 1 is a dense framework whereas compound 2 is a porous one, though both compounds have an infinite two-dimensional (2D) layer structure. Compounds 1 and 2 are the first examples of pyridine dicarboxylic acid N-oxide introduced into the alkaline earth metal–organic framework. |
| Databáze: | OpenAIRE |
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