Thermodynamic properties of liquid enantiomers I. Enthalpies of vaporization of fenchones, α-methylbenzylamines, and limonenes at 298.15 K
Autor: | Yoshihiro Saito, Kazuhito Kusano, Zadjia Atik |
---|---|
Rok vydání: | 1987 |
Předmět: | |
Zdroj: | The Journal of Chemical Thermodynamics. 19:99-102 |
ISSN: | 0021-9614 |
Popis: | Molar enthalpies of vaporization Δ l g H m of liquid enantiomers were measured by microconduction and carrier-gas flow-type calorimetry. Δ l g H m results at 298.15 K for (+)- and (−)-fenchone, (+)-, (−)-, and (±)-α-methylbenzylamine, and (+)- and (−)-limonene are given. Values for the chiral discrimination for the liquid-to-gas transition in α-methyl-benzylamine were derived. |
Databáze: | OpenAIRE |
Externí odkaz: |