Resonant electron capture by Captopril molecules
| Autor: | P. V. Shchukin, Mars V. Muftakhov |
|---|---|
| Rok vydání: | 2019 |
| Předmět: |
chemistry.chemical_classification
Dipeptide 010405 organic chemistry Electron capture Biomolecule Substituent General Chemistry 010402 general chemistry 01 natural sciences 0104 chemical sciences Ion Crystallography chemistry.chemical_compound chemistry Fragmentation (mass spectrometry) Molecule Cysteine |
| Zdroj: | Russian Chemical Bulletin. 68:1675-1683 |
| ISSN: | 1573-9171 1066-5285 |
| DOI: | 10.1007/s11172-019-2611-3 |
| Popis: | The modified dipeptide, Captopril, was studied to determine the effect of lateral functional groups on the decay of biomolecules in resonant reactions of electrons with molecules. The main channels of fragmentation of negative molecular ions were determined, and the characteristic fragment ions were identified. The SH fragment of the lateral substituent of cysteine plays an important role similarly as does the carboxyl fragment of aspartic acid in oligopeptides. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full text from SpringerLink