First Spectroscopical Evidence of a Dioxomethylene Intermediate in the Reaction of CO2 with Cp2Zr(H)Cl: A 13C NMR Study

Autor:	Nils E. Schlörer and, Stefan Berger
Rok vydání:	2001
Předmět:	Inorganic Chemistry In situ Stereochemistry Computational chemistry Chemistry Reagent Organic Chemistry Physical and Theoretical Chemistry Carbon-13 NMR
Zdroj:	Organometallics. 20:1703-1704
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om000598j
Popis:	An in situ variable-temperature 13C NMR study on the mechanism of the reaction of Schwartz's reagent, Cp2Zr(H)Cl, with labeled 13CO2 was performed. In the course of the investigations, for the firs...
Databáze:	OpenAIRE
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