A Dimeric Hydride-Bridged Complex with Geometrically Distinct Iron Centers Giving Rise to an S = 3 Ground State

Autor:	Anne K. Hickey, Jeremy M. Smith, Jordan A. DeGayner, Joshua Telser, T. David Harris, Sean A. Lutz, Juan A. Valdez-Moreira, Maren Pink, Stephen Hill, Samuel M. Greer
Rok vydání:	2019
Předmět:	Iron hydride Hydride Chemistry General Chemistry 010402 general chemistry 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Characterization (materials science) Crystallography Colloid and Surface Chemistry Tetrahedron Ground state
Zdroj:	Journal of the American Chemical Society. 141:11970-11975
ISSN:	1520-5126 0002-7863
Popis:	Structural and spectroscopic characterization of the dimeric iron hydride complex [Ph2B(tBuIm)2FeH]2 reveals an unusual structure in which a tetrahedral iron(II) site (S = 2) is connected to a squa...
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a45248fd615210066ba72dd4e5cce0ca https://doi.org/10.1021/jacs.9b04389 Zobrazit plný text záznamu