A Small-Angle X-ray Scattering Study of the Structure of Gels Formed by Poly(oxyethylene)−Poly(oxypropylene) Diblock Copolymers in Water

Autor:	Ian W. Hamley, Valeria Castelletto, Johan Fundin, Colin Price, Zhuo Yang, Colin Booth
Rok vydání:	2002
Předmět:	Langmuir Materials science Copolymer composition Aqueous solution Scattering Small-angle X-ray scattering Analytical chemistry Surfaces and Interfaces Radius Condensed Matter Physics Polymer chemistry Electrochemistry Copolymer General Materials Science Static light scattering Spectroscopy
Zdroj:	Langmuir. 18:1051-1055
ISSN:	1520-5827 0743-7463
DOI:	10.1021/la011035v
Popis:	The structures of gels formed by a number of poly(oxyethylene)−poly(oxypropylene) diblock copolymers in aqueous solution have been investigated using small-angle X-ray scattering. Body-centered and face-centered cubic micellar phases were identified depending on the copolymer composition. The micellar radius in the gel is compared to that in dilute solution (obtained from static light scattering) and to predictions from scaling theory. The gel structures are compared to those reported previously for poly(oxyethylene)−poly(oxybutylene) diblocks in water (Hamley et al. Langmuir 2000, 16, 2508).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a42d6bcb5fed6a0706ca9d75a51f90b8 https://doi.org/10.1021/la011035v Zobrazit plný text záznamu