Rapid analysis of 90Sr in cattle bone and tooth samples by inductively coupled plasma mass spectrometry
| Autor: | Manabu Fukumoto, Jo Aoki, Toshihiko Suzuki, Motoki Terashima, Kayo Yanagisawa, Yasushi Kino, Akihiro Kitamura, Keiichi Sasaki, Hironobu Abe, Hisashi Shinoda, Ken Osaka, Yoshinaka Shimizu, Kenso Fujiwara, Mirei Chiba, Toshitaka Oka, Kazuma Koarai, Makoto Matsueda, Atsushi Takahashi, Tsutomu Sekine |
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| Rok vydání: | 2021 |
| Předmět: |
Detection limit
Chromatography Chemistry 010401 analytical chemistry Extraction (chemistry) 02 engineering and technology 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Analytical Chemistry Matrix (chemical analysis) Isobar Isobaric process 0210 nano-technology Inductively coupled plasma mass spectrometry Spectroscopy |
| Zdroj: | Journal of Analytical Atomic Spectrometry. 36:1678-1682 |
| ISSN: | 1364-5544 0267-9477 |
| DOI: | 10.1039/d1ja00086a |
| Popis: | Rapid analysis of 90Sr in bone and tooth samples of cattle was achieved by inductively coupled plasma mass spectrometry (ICP-MS) coupled with mass-shift and solid-phase extraction techniques. The mass-shift technique with the O2 reaction mode of ICP-MS was applied to the mass shift of isobaric element 90Zr, effectively removing its interference. The solid-phase extraction technique using a Sr resin, which is a polymeric resin supported by 4,4′(5′)-bis-t-butylcyclohexano-18-crown-6, quantitatively separated 90Sr from the interfering matrix elements and isobars in the bone and tooth samples. The activity concentrations determined by ICP-MS were comparable with those determined by the conventional radiometric method. However, the limit of detection in the ICP-MS measurement of 0.1 g samples was lower than that in the radioactivity measurement. The analytical time of the ICP-MS method was shortened from 20 days to 11 h, compared with the radiometric method. Therefore, the ICP-MS method can be a rapid and useful procedure for determination of 90Sr in small bone and tooth samples taken from terrestrial animals. |
| Databáze: | OpenAIRE |
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