Analyzing anode and cathode products obtained by the electrolysis of Y-Ba-Cu-O and Y-Ba-Cu-K-O systems

Autor:	L. A. Klinkova, V. I. Nikolaichik
Rok vydání:	2014
Předmět:	Electrolysis Materials science Alkaline water electrolysis Analytical chemistry Oxide General Physics and Astronomy Cathode law.invention Anode chemistry.chemical_compound Electron diffraction chemistry law High-temperature electrolysis Polymer electrolyte membrane electrolysis
Zdroj:	Bulletin of the Russian Academy of Sciences: Physics. 78:864-867
ISSN:	1934-9432 1062-8738
Popis:	Energy dispersive X-ray spectroscopy (EDX) and electron diffraction and high-resolution electron microscopy are used to study the composition and structure of anode and cathode deposits formed during the high temperature (950°C) electrolysis of the Y-Ba-Cu-O system and low temperature (450°C) electrolysis of the Y-Ba-Cu-K-O system. It is found for the first time that an oxide with the YBa2Cu3Oy structure (123 phase) is synthesized during the high temperature electrolysis of Y0.02Ba0.30Cu0.70Oy and Y0.02Ba0.25Cu0.75Oy melts. The 123 phase is not synthesized during low temperature electrolysis, where melts are formed from Y2O3, BaO2, CuO, and KOH. Two new Pt-containing oxides with hexagonal structure are found in the products of high temperature electrolysis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a41ced85c568449f66d0c555fd9d1386 https://doi.org/10.3103/s1062873814090184 Zobrazit plný text záznamu Full text from SpringerLink