ChemInform Abstract: Reactions of (RP)- and (SP)-tert-Butylphenylphosphinobromidates and tert-Butylphenylthionophosphinochloridates with Heteroatom Nucleophiles; Preparation of P-Chiral Binol Phosphinates and Related Compounds

Autor:	Richard K. Haynes, Wai-Kuen Chan, Ka-Yee Chan, Lam-Lung Yeung, Ian D. Williams, Tin-Lok Au-yeung
Rok vydání:	2001
Předmět:	chemistry.chemical_compound Nucleophile Chemistry Heteroatom Organic chemistry Phenol General Medicine Medicinal chemistry
Zdroj:	ChemInform. 32
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200114186
Popis:	Reaction of (RP)- and (SP)-tert-butylphenylphosphinobromidates and tert-butylphenylthionophosphinochloridates with metallated phenol and BINOL alkoxides, thioalkoxides, amides and enolates leading with clean inversion at phosphorus to phosphinates, phosphinothiolates and phosphinoamidates, and the corresponding thionophosphorus compounds are described.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a41c8e4e30d7b7ac82ed27d1e5c12c00 https://doi.org/10.1002/chin.200114186 Zobrazit plný text záznamu Plný text