Self-assembly of ion-paired electron-transfer centers in a clay-modified electrode

Autor:	Polycarpos Falaras, T. J. Pinnavaia, D. Petridis
Rok vydání:	1992
Předmět:	chemistry.chemical_classification Stereochemistry Inorganic chemistry Salt (chemistry) Electrochemistry Ion Inorganic Chemistry Electron transfer chemistry Electrode Graphite Self-assembly Physical and Theoretical Chemistry Cyclic voltammetry
Zdroj:	Inorganic Chemistry. 31:3530-3533
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic00043a010
Popis:	Electrochemical properties are reported for a montmorillonite-modified graphite electrode intersalated by the complex salt [Fe(bpy) 3 ] 2 Fe(CN) 6 ] at loadings in excess of the cation-exchange capacity of the clay. The presence of a multilayer assembler in the clay galleries was indicated by a basal spacing of ∼27 A, as compared to 17 A for homoionic Fe(bpy) 3 4- -montmorillonite.
Databáze:	OpenAIRE
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