Enantiospecific synthesis of 8-epipuupehedione from ( R )-(−)-carvone
Autor: | Basudeb Achari, Chandana Giri, Sujaya Sengupta, Asish Kr. Banerjee, Soumen Maiti |
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Rok vydání: | 2001 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 42:2389-2391 |
ISSN: | 0040-4039 |
DOI: | 10.1016/s0040-4039(01)00153-8 |
Popis: | An enantiospecific synthesis of the antitumor marine sponge metabolite puupehedione (2a) and its C8-epimer 2b as their methylenedioxy derivatives 8a and 8b was achieved through concomitant O-allyl deprotection and electrocyclization of 20 derived from (−)-carvone. |
Databáze: | OpenAIRE |
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