Enantiospecific synthesis of 8-epipuupehedione from ( R )-(−)-carvone

Autor: Basudeb Achari, Chandana Giri, Sujaya Sengupta, Asish Kr. Banerjee, Soumen Maiti
Rok vydání: 2001
Předmět:
Zdroj: Tetrahedron Letters. 42:2389-2391
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00153-8
Popis: An enantiospecific synthesis of the antitumor marine sponge metabolite puupehedione (2a) and its C8-epimer 2b as their methylenedioxy derivatives 8a and 8b was achieved through concomitant O-allyl deprotection and electrocyclization of 20 derived from (−)-carvone.
Databáze: OpenAIRE