Palladium-catalyzed formation of secondary and tertiary amines from aryl dihalides with air-stable ferrocenyl tri- and diphosphines: Synthesis and X-ray structure of efficient catalysts beyond [PdCl2(DPPF)]

Autor:	Jean-Cyrille Hierso, Hélène Cattey, Paul J. Low, Mélanie Platon, Howard J. Spencer, Sophal Mom
Rok vydání:	2014
Předmět:	Denticity Meso compound Process Chemistry and Technology Aryl chemistry.chemical_element General Chemistry Medicinal chemistry Catalysis chemistry.chemical_compound Aniline chemistry Ferrocene Diphosphines Organic chemistry Selectivity Palladium
Zdroj:	Catalysis Communications. 51:10-14
ISSN:	1566-7367
Popis:	Robust, air-stable tridentate and bidentate ferrocenylphosphines 1,2-bis(diphenylphosphino)-1′-(diisopropylphosphino)-4-tert-butylferrocene, L5, and 1,1′-bis(diisopropylphosphino)-3,3′-bis(tert-butyl)ferrocene, L9, combined with 1 mol% of [PdCl(η3-C3H5)]2 led to two new catalytic systems which allow the coupling of aniline derivatives with mono- and dihaloarenes to form functionalized diarylamines and triarylamines. The excellent selectivity of the reactions avoids the deleterious dehalogenation of the substrates and products. The X-ray structure characterization of the related complex [PdCl2(L9)] is reported in which ligand L9 in its meso form is significantly distorted.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a3da74c5604aa47ecbf437745d929076 https://doi.org/10.1016/j.catcom.2014.03.012 Zobrazit plný text záznamu Full Text from ScienceDirect