Tuning the Vacancy Concentration in Lithium Germanium Antimony Tellurides—Influence on Phase Transitions, Lithium Mobility, and Thermoelectric Properties
| Autor: | Oliver Oeckler, Paul Heitjans, Markus Nentwig, Andre Düvel, Matthias Jakob, Stefan Schwarzmüller, Thorsten Schröder, Alexander Kuhn |
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| Rok vydání: | 2018 |
| Předmět: |
Phase transition
Materials science General Chemical Engineering chemistry.chemical_element Germanium 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences chemistry Antimony Vacancy defect Thermoelectric effect Materials Chemistry Solid solution series Physical chemistry Lithium 0210 nano-technology |
| Zdroj: | Chemistry of Materials. 30:7970-7978 |
| ISSN: | 1520-5002 0897-4756 |
| Popis: | In the solid solution series Li2–xGe3+1/2xSb2Te7 and Li2–xGe11+1/2xSb2Te15 (0 ≤ x ≤ 2), the heterovalent substitution gradually changes the vacancy concentration on the cation position from 0% (for... |
| Databáze: | OpenAIRE |
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