Mono- and Di(dechloromethylthioylation) of Dichloromethylarenes with S-Methyl Diethylthiophosphinate

Autor:	Igor S. Antipin, Mukattis B. Gazizov, Yu. S. Kirillina, Rafail A. Khairullin, S. Yu. Ivanova, G. D. Valieva
Rok vydání:	2019
Předmět:	chemistry.chemical_classification 010405 organic chemistry chemistry.chemical_element General Chemistry Electronic structure 010402 general chemistry 01 natural sciences Medicinal chemistry Sulfur 0104 chemical sciences chemistry Group (periodic table) Thiol Carbon
Zdroj:	Doklady Chemistry. 489:257-260
ISSN:	1608-3113 0012-5008
DOI:	10.1134/s0012500819110016
Popis:	The attack of the thiol sulfur atom (P–SMe) on the methine carbon as the main route of the new reaction of dichloromethylarenes with S-methyl diethylthiophosphinate has been predicted and experimentally confirmed on the basis of the electronic structure of the S-alkyl esters of P(IV) acids. The processes of the mono- and di(dechloromethylthioylation) of dichloromethyl group have been realized. A new approach to the synthesis of the arenecarbaldehyde dimethyl dithioacetals has been developed avoiding the use of gaseous highly toxic methyl mercaptan.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a39dbc4f21b9beceec3042b14f592686 https://doi.org/10.1134/s0012500819110016 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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