Polyol-mediated synthesis of ZnO nanoparticle-assembled hollow spheres/nanorods and their photoanode performances
Autor: | Eui Jung Kim, Dinh Khoi Dang, Sung Hong Hahn, Soon Wook Kim, Tri Khoa Nguyen, Seung Hyun Hur, Doan Van Thuan |
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Rok vydání: | 2016 |
Předmět: |
chemistry.chemical_classification
Materials science General Chemical Engineering Diethylene glycol Nanotechnology 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Catalysis Dye-sensitized solar cell chemistry.chemical_compound chemistry Polyol Nanorod SPHERES 0210 nano-technology Current density Ethylene glycol |
Zdroj: | Korean Journal of Chemical Engineering. 34:495-499 |
ISSN: | 1975-7220 0256-1115 |
DOI: | 10.1007/s11814-016-0283-3 |
Popis: | ZnO nanoparticle-assembled hollow spheres (raspberry-like) and elliptical nanorods (rice-like) were synthesized via a facile polyol process. Employing ethylene glycol as a polyol led to a ZnO nanoparticle-assembled hollow sphere structure, while diethylene glycol resulted in an elliptical nanorod structure. The ZnO hollow spheres had a higher Brunauer-Emmett-Teller (BET) surface area, better dye adsorption, more incident light trapping, and lower defect density than the ZnO elliptical nanorods. The ZnO hollow sphere-based dye-sensitized solar cells (DSSCs) exhibited a three-times higher current density than the ZnO elliptical nanorod-based DSSCs. |
Databáze: | OpenAIRE |
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