Polyol-mediated synthesis of ZnO nanoparticle-assembled hollow spheres/nanorods and their photoanode performances

Autor: Eui Jung Kim, Dinh Khoi Dang, Sung Hong Hahn, Soon Wook Kim, Tri Khoa Nguyen, Seung Hyun Hur, Doan Van Thuan
Rok vydání: 2016
Předmět:
Zdroj: Korean Journal of Chemical Engineering. 34:495-499
ISSN: 1975-7220
0256-1115
DOI: 10.1007/s11814-016-0283-3
Popis: ZnO nanoparticle-assembled hollow spheres (raspberry-like) and elliptical nanorods (rice-like) were synthesized via a facile polyol process. Employing ethylene glycol as a polyol led to a ZnO nanoparticle-assembled hollow sphere structure, while diethylene glycol resulted in an elliptical nanorod structure. The ZnO hollow spheres had a higher Brunauer-Emmett-Teller (BET) surface area, better dye adsorption, more incident light trapping, and lower defect density than the ZnO elliptical nanorods. The ZnO hollow sphere-based dye-sensitized solar cells (DSSCs) exhibited a three-times higher current density than the ZnO elliptical nanorod-based DSSCs.
Databáze: OpenAIRE