Structure of Radicals Produced by γ-Radiolysis. Part 3. Radicals Derived from Adamantane, Adamantyl Derivatives, and Diamantane

Autor:	George J. Jun. Hyfantis, A. Campbell Ling
Rok vydání:	1974
Předmět:	Radical Adamantane Organic Chemistry Kinetics General Chemistry Resonance (chemistry) Photochemistry Catalysis law.invention chemistry.chemical_compound chemistry Computational chemistry law Radiolysis Halogen Electron paramagnetic resonance Diamantane
Zdroj:	Canadian Journal of Chemistry. 52:1206-1215
ISSN:	1480-3291 0008-4042
Popis:	The effects of γ-radiolysis on adamantane, perdeuterated adamantane, diamantane, 1- and 2-chloroadamantane, 1- and 2-bromoadamantane, 1-cyanoadamantane, 1- and 2-adamantanol, 1- and 2-adamantylamine have been examined via electron spin resonance techniques, and the nature of the predominant species produced is discussed. Spin-scavenging experiments using 2-methyl-2-nitrosopropane have been used, together with previously reported Br2 scavenging experiments, to identify the nature of the predominant species produced when purified solid adamantane is subjected to radiolysis. Data indicate that this is the 1-adamantyl radical. A possible reason for the controversial nature of data on this subject reported previously by other investigators is given.
Databáze:	OpenAIRE
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