Crystal size effect on the compressibility of nano-crystalline uranium dioxide

Autor: C.E. Zvoriste-Walters, Arne Janssen, S. Heathman, J. Spino, R. Jovani-Abril, Roberto Caciuffo
Rok vydání: 2013
Předmět:
Zdroj: Journal of Nuclear Materials. 435:123-127
ISSN: 0022-3115
Popis: The crystal size dependence of the bulk modulus of nano-crystalline uranium dioxide is investigated by means of in situ high pressure X-ray diffraction. Samples with average particle sizes of 4, 6 and 34 nm as measured from high resolution TEM images were studied up to 27 GPa revealing that all three nano-crystalline UO2 samples show a drastic decrease of bulk modulus with decreasing particle size. The influence of choosing the right EOS to fit the compression data is also discussed.
Databáze: OpenAIRE