Iron(ii)-chloride-catalyzed regioselective azidation of allenamides with TMSN3

Autor:	Yongchun Liu, Zhigang Zhao, Xiaoxiao Li, Na Ding, Xiaoju Tan
Rok vydání:	2020
Předmět:	Chemistry Metals and Alloys Regioselectivity General Chemistry Combinatorial chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound Materials Chemistry Ceramics and Composites Stereoselectivity Iron(II) chloride Azide
Zdroj:	Chemical Communications. 56:7507-7510
ISSN:	1364-548X 1359-7345
DOI:	10.1039/c9cc10056c
Popis:	In this study, we developed a new cost-effective and efficient route for accessing allyl azides: iron(ii)-chloride-catalyzed regioselective azidation of allenamides with TMSN3. This process is highly regio- and stereoselective, affording (E)-allyl azides in good to excellent yields. Due to the versatility of the azide group, these products can be transformed in situ to allyl triazoles and allyl amines, facilitating numerous subsequent chemical modifications.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a35a13ed4c6083941d477014bb68ad4e https://doi.org/10.1039/c9cc10056c Zobrazit plný text záznamu