Recognition of metal complex guests: supramolecular extraction of water-soluble lanthanide complexes by biological lasalocid ionophore
| Autor: | Hiroshi Tsukube, Hideyo Takeishi, Zenko Yoshida |
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| Rok vydání: | 1996 |
| Předmět: |
Tris
Lanthanide Chemistry Extraction (chemistry) Inorganic chemistry Supramolecular chemistry Ionophore Combinatorial chemistry Inorganic Chemistry Metal chemistry.chemical_compound Water soluble visual_art Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Lasalocid |
| Zdroj: | Inorganica Chimica Acta. 251:1-3 |
| ISSN: | 0020-1693 |
| DOI: | 10.1016/s0020-1693(96)05345-5 |
| Popis: | Naturally occurring lasalocid ionophore was first demonstrated to extract water-soluble lanthanide tris(acetylacetonates) via inner-sphere complexation into CCl4. This offered higher extraction abilities for small Er3+ and Dy3+ complexes than for large Pr3+ and La3+ complexes. Since the lasalocid extracted lanthanide cations themselves non-selectively, this ‘metal complex recognition’ has new and interesting possibilities in separation and sensing of valuable lanthanides. |
| Databáze: | OpenAIRE |
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