Elementary Stages of Photochemical Reactions of Substituted 2,6-Diphenyl-para-benzoquinones with Thiols

Autor:	D. N. Gurulev, L. V. Palatkina, V. I. Porkhun, E. V. Porkhun
Rok vydání:	2018
Předmět:	Dibenzofuran chemistry.chemical_compound chemistry 010405 organic chemistry Ethanethiol Photodissociation General Chemistry 010402 general chemistry Photochemistry 01 natural sciences Two stages 0104 chemical sciences Quinone
Zdroj:	Russian Journal of General Chemistry. 88:1580-1583
ISSN:	1608-3350 1070-3632
Popis:	Using the effects of chemical polarization of nuclei, mechanism and elementary stages of photochemical reduction of 2,6-diphenyl-1,4-benzoquinone with thiols have been elucidated. The studied quinone is reduced with ethanethiol in two stages (transfer of electron followed by proton transfer). The final photolysis product is a derivative of dibenzofuran.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a34f8bf3634d586581fd9fdfdd59ee49 https://doi.org/10.1134/s1070363218080042 Zobrazit plný text záznamu Plný text ve formátu PDF