Aggregation behavior of two-arm fullerene-containing poly(ethylene oxide)
| Autor: | T. Song, Kam Chiu Tam, Suat Hong Goh, Swee Yong Lee, Sheng Dai |
|---|---|
| Rok vydání: | 2003 |
| Předmět: |
chemistry.chemical_classification
Aggregation number Polymers and Plastics Ethylene oxide Organic Chemistry Oxide Analytical chemistry Polymer Thermogravimetry Gel permeation chromatography End-group chemistry.chemical_compound chemistry Chemical engineering Materials Chemistry Fourier transform infrared spectroscopy |
| Zdroj: | Polymer. 44:2529-2536 |
| ISSN: | 0032-3861 |
| DOI: | 10.1016/s0032-3861(03)00107-1 |
| Popis: | A water-soluble two-arm fullerene-containing poly(ethylene oxide) (PEO) was synthesized through isocyanate-hydroxy condensation reaction with fullerenol as a molecular core and characterized by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, thermogravimetry, and matrix-assisted laser desorption ionization time of flight mass spectrometry. The aggregation behavior of the resulting amphiphilic polymer in water, THF, and DMF, was studied by gel permeation chromatography, laser light scattering, and transmission electron microscopy. The polymer forms spherical aggregates with an aggregation number around 540–1020. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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