ChemInform Abstract: PYRIDINES AS LEAVING GROUPS IN SYNTHETIC TRANSFORMATIONS- CONVERSION OF AMINES INTO ESTERS

Autor:	Hamid Sheikh, Urban Gruntz, David H. Kenny, Alan R. Katritzky, Marcos Caroli Rezende
Rok vydání:	1978
Předmět:	chemistry.chemical_compound Tetrafluoroborate Primary (chemistry) chemistry Sodium chemistry.chemical_element General Medicine Carboxylate Pyridinium Medicinal chemistry Pyrolysis Benzoates
Zdroj:	Chemischer Informationsdienst. 9
ISSN:	0009-2975
DOI:	10.1002/chin.197807167
Popis:	Primary amines RCH2NH2 are converted into acetates (MeCO2CH2R) and benzoates (PhCO2CH2R) in a two-step process: (a) reaction with triphenylpyrylium tetrafluoroborate and (b) pyrolysis of the pyridinium tetrafluoroborate so obtained with the sodium carboxylate.
Databáze:	OpenAIRE
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