Reversible adsorption deformation of layered adsorbents at high pressures and temperatures

Autor:	A. A. Pribylov, N. S. Kazbanov, D. B. Guljamova, I. A. Kalinnikova, S. Z. Muminov, L. G. Shekhovtsova
Rok vydání:	2008
Předmět:	Chromatography Chemistry Reversible adsorption Sodium technology industry and agriculture Analytical chemistry chemistry.chemical_element Inverse temperature General Chemistry chemistry.chemical_compound Adsorption Montmorillonite Volume (thermodynamics) Pyridinium Deformation (engineering)
Zdroj:	Russian Chemical Bulletin. 57:2460-2466
ISSN:	1573-9171 1066-5285
Popis:	Isotherms of excessive adsorption of N2 and Ar on three montmorillonite samples (natural sodium (NaMt) and ion-exchange pyridinium (PyMt) and polyhydroxyaluminum (PGAMt)) were measured in the pressure interval from 0.1 to 60 MPa and at temperatures 303, 343, 373, and 400 K. The results of measurements showed the inverse temperature dependence of the measured isotherms of excessive adsorption at elevated pressures and temperatures: for the isotherms at higher temperatures the amounts adsorbed exceed the values measured at lower temperatures. The deformation of montmorillonites with the temperature increase results in an increase in the adsorption volume of the adsorbent.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a32c6c7b0784df66e25373bf6f2a5d7f https://doi.org/10.1007/s11172-008-0354-7 Zobrazit plný text záznamu Full text from SpringerLink