Transformation of polymethylenesilanes under the influence of aluminum chloride

Autor:	N. S. Nametkin, K. S. Pushchevaya, V. M. Vdovin
Rok vydání:	1967
Předmět:	Trimethylsilyl Inorganic chemistry chemistry.chemical_element Alkyl radicals Disproportionation General Chemistry Ring (chemistry) Chloride chemistry.chemical_compound chemistry Polymerization Aluminium Yield (chemistry) Polymer chemistry medicine medicine.drug
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 16:2413-2417
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00911855
Popis:	1. Dimethylhexamethylenesilane is polymerized under the influence of aluminum chloride with an opening of the ring. Methylethylpentamethylenesilane, isomeric with it, undergoes disproportionation of the alkyl radicals under the same conditions. 2. Dimethylpentamethylenesilane (80% yield) and dimethylhexamethylenesilane (1–3% yield) are formed from α,Ω-bis(trimethylsilyl)penta- and -hexamethylene under the influence of aluminum chloride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a32ba4953e826ef0489a1ea02e450e9a https://doi.org/10.1007/bf00911855 Zobrazit plný text záznamu Full text from SpringerLink