| Popis: |
The complexity of heterogeneous-catalytic reactions often leads to a rejection of kinetic equations based on the mass action law in favor of kinetic equations, the form of which is determined by the Langmuir���Hinshelwood mechanism. In this article is proposed the methodology of processing on a personal computer of experimental data to determine the possible mechanism of the reaction, envisaging various variants of adsorption of the reagents and reaction products. The step-by-step algorithm offers the development of an Excel program that is designed to calculate the reaction rate constant, the adsorption coefficients of the reaction components, the pre-exponential factor, the activation energy and the heat of adsorption for catalytic heterogeneous processes occurring in the kinetic region. |
