Organosilicon-Assisted Transformation of Living Anionic into Living Cationic Polymerization

Autor:	Hideki Sakurai, Takanobu Sanji, Yasuhiro Muto, Daisuke Sunaga
Rok vydání:	2003
Předmět:	End-group Anionic addition polymerization Materials science Polymers and Plastics Polymerization Silylation Organic Chemistry Polymer chemistry Materials Chemistry Cationic polymerization Ionic polymerization Living cationic polymerization Living anionic polymerization
Zdroj:	Macromolecular Rapid Communications. 24:340-343
ISSN:	1022-1336
DOI:	10.1002/marc.200390053
Popis:	A novel method is described for transforming an anionic polymerizationprocess cationic polymerization process assisted by organosilyl groups. The reaction of the p-tolydimethylsilyl end group of polystyreneand triflouromethanesulfonic acid produced a silyl triflate' end ' group that served as a macrointiator for the si-O in the block copolymers underwent specific cleavage , by reaction with tetrabutylammonium fluoride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a2fbd7fda5be84cb3977f5ce9ee54432 https://doi.org/10.1002/marc.200390053 Zobrazit plný text záznamu Plný text