Benzyne formation and the stepwise decomposition of benzenediazonium-2-car☐ylate: A re-investigation

Autor:	K. G. Mason, Harry Heaney, P. Christopher Buxton, Mark Fensome
Rok vydání:	1995
Předmět:	chemistry.chemical_compound chemistry Nucleophile Organic Chemistry Drug Discovery Carbon dioxide chemistry.chemical_element Photochemistry Biochemistry Decomposition Nitrogen Aryne Chemical decomposition
Zdroj:	Tetrahedron. 51:2959-2968
ISSN:	0040-4020
DOI:	10.1016/0040-4020(95)00028-7
Popis:	A study of the decomposition reactions of benzenediazonium-2-car☐ylate, carried out in a number of mixed nucleophilic solvents, shows that a number of mechanistic pathways can operate simultaneously and can afford, in addition to products derived from benzyne, products derived from the 2-car☐yphenyl cation and the 2-car☐yphenyl radical: benzyne formation is favoured in halogenated solvents and occurs by the concerted loss of nitrogen and carbon dioxide.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::a2d02e605065e7ac75f2b87b224579c7 https://doi.org/10.1016/0040-4020(95)00028-7 Zobrazit plný text záznamu Full Text from ScienceDirect